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In 2013 he edited "Britain and the Holy See: A Celebration of 1982 and the Wider Relationship", which set out the proceedings of the 2012 Rome Colloquium on the relationship between Britain and the Holy See. Contributors include Professor Eamon Duffy, Professor Judith Champ, Cardinal Vincent Nichols, Cardinal Keith Patrick O'Brien, and Cardinal Cormac Murphy-O'Connor.

Returning to the FCO, he was Head of the European Defence Section in the Security Policy Department between 1998–2000. He was then assistant Private Secretary to the Prince of Wales 2000–03, Deputy Head of Mission, Havana, 2003–06 and Ambassador to Bolivia 2007–11 before being appointed to the Holy See. He presented his credentials to Pope Benedict XVI on 9 September 2011. In 2016, he returned to the FCO as Deputy Director for the Americas and Head of the South America Department. He became Deputy Director and Head of the Latin America Department in 2018.

Baker was appointed MVO in 2003 for services to the Prince of Wales, and OBE in 2010.

Baker was educated at Dulwich College and Gonville and Caius College, Cambridge where he gained a first class degree in history. After a brief period as researcher in the Conservative Research Department he joined the Foreign and Commonwealth Office (FCO) in 1989. After early overseas postings in Prague and Bratislava he took a research sabbatical in Verona (from 1996–97) studying Italian and European history.

Nigel Marcus Baker OBE MVO (born 9 September 1966) is a diplomat, who was formerly British Ambassador to Bolivia and Ambassador to the Holy See. He is currently Head of the Latin America Department at the Foreign and Commonwealth Office.