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In January 2019 (during the 2019 Venezuelan presidential crisis), the National Assembly of Venezuela appointed Gustavo Tarre Briceño as representative to the OAS, an international organization which does not recognize Nicolás Maduro as president. On April 9, 2019, the OAS voted 18 to 9, with six abstentions, to accept Tarre as the ambassador from Venezuela until new presidential elections can be held.

Tarre's appointment encouraged similar actions against the Maduro government by other international bodies. On April 10, 2019 the International Monetary Fund cut off Venezuelan access until a majority of its members recognized a Maduro or Guaidó representative, and the United States Vice President Mike Pence requested that the United Nations replace ongoing ambassador Samuel Moncada with a Guaidó-aligned one.

He was Venezuela's deputy foreign minister until June 2017, when he succeeded Delcy Rodriguez as Venezuela's Foreign Minister. On August 2, 2017, following the 2017 Venezuelan Constituent Assembly election, President Nicolás Maduro appointed former Vice President Jorge Arreaza to replace Moncada as the new Foreign Affairs Minister.

Moncada assumed the Vice-Ministry for North America, and then replaced Delcy Rodríguez as Foreign Affairs Minister during the 2017 Constituent Assembly election. After the elections were over, President Nicolás Maduro appointed former Vice President Jorge Arreaza as his successor, for which Moncada returned to exercise his functions as Vice Minister and Ambassador of Venezuela to the OAS.

Between 2004 and 2006, he was Minister of Higher Education of President Hugo Chavez and director of the History School of the Central University of Venezuela. Moncada was Ambassador of Venezuela to the United Nations in 2013. He also was Venezuela's ambassador to the United Kingdom of Great Britain and Northern Ireland.

Samuel Reinaldo Moncada Acosta (born 13 June 1959) is a Venezuelan historian, politician and diplomat currently serving as Permanent Representative of Venezuela to the United Nations since 2017 and formerly served as Alternate Representative of Venezuela to the Organization of American States from 2017 to 2019.